What you are trying to do is called overburning. For this you need 3 things:
Hardware (aka cd recorder) able of overburning - most recorders nowdays can overburn safely till atleast 94min; still it could be a limiting factor. What is the burner you will be using?
Recording software - no problem there Nero can do it as long as you have the latest version (some older version had problems with overburning)
To be able to overburn with Nero you have to enable this feature first. Go to File - Preferences - Expert features and enable overburning up to what your burner can do either 94min or most probably 99min.