If it's now showing as a DVD-RAM & Pioneer 111L then that's fine.
What you've done is cross-flashed it from the 111D to the 111L which gives DVD-RAM writing capability & auto-bitsetting on DVD+R media. The firmware version you used from the TDB website would have been 8.xx which is the 111L firmware. If the burner is an internal then you should have used the INT firmware version.
You've checked the DMA incorrectly BTW. The mode 5 one is probably your HDD on the Primary channel. The Pio will not show as mode 5 as it's mode 4 maximum.
WIth 2 IDE Channels the Pio should be set as master on the Secondary channel with an 80wire IDE cable.