I don't know if version 5 supports Windows XP.....it has been succeeded by two versions already
PowerQuest DriveImage 2002 (v6.0)
PowerQuest DriveImage v7.0
As Da_Taxman said, Ghost is a great option. I use Ghost 2003 because all I need is a floppy disk to backup/restore images and that's the way I like it. I've heard that Acronis TrueImage 6.0 is also a good alternative, but I haven't really tested it out.