Creating an new dvd


Im totally new in this, so i hope that somebody can help me. Ive got an dvd with 1 chapters (its an music dvd). It has 6 PGCs. 1 and 4 are the same (with an red block before it), 2 and 5 are the same and 3 and 6 are also the same.
Only the ones with an red block before it contains movie files. (16 titles)
Now there are 27 numbers on that dvd, and i want for every number an new chapter, so that people in the menu can choose which chapter ( or number ) they want to see. so that they simply can select the chapter which compares with that number.
I`ve understood that it is possible with this program, but can someone tell me how please?

I`ve dvd remake pro 3.1.4

thx in advance