cd writers wouldn't be any good if we couldn't copy psx games! there's some stuff that you need that might be too hard for you to do on your own.
list of shit:
1. software, any of these will work fine - cdrwin, nero burning rom, clonecd, discjuggler. there's lots more proggies i'm sure i forgot, but any of these is good.
- modchip - ahhh yes, the modchip. this little circuit allows to play copied games. without one, your copies won't do a thing. this is the hardest thing to do. you need some basic electrical experience to put this baby in. i made mine myself and soldered it myself, but i don't know if you have the electrical skills to do that.
if you don't, you can buy one at modchip.com, and try and solder it in yourself. good luck with it!